<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Sinclair, Matthew J.G.</style></author><author><style face="normal" font="default" size="100%">Roig, Nil</style></author><author><style face="normal" font="default" size="100%">Gyton, Matthew R.</style></author><author><style face="normal" font="default" size="100%">Tsoureas, Nikolaos</style></author><author><style face="normal" font="default" size="100%">Cloke, F. Geoffrey N.</style></author><author><style face="normal" font="default" size="100%">Alonso, Mercedes</style></author><author><style face="normal" font="default" size="100%">Chaplin, Adrian B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">T-Shaped Palladium and Platinum {MNO}10 Nitrosyl Complexes</style></title><secondary-title><style face="normal" font="default" size="100%">Inorganic Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">2024</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">American Chemical Society</style></publisher><volume><style face="normal" font="default" size="100%">63</style></volume><pages><style face="normal" font="default" size="100%">1709 - 1713</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">The synthesis and characterization of a homologous series of T-shaped {MNO}10 nitrosyl complexes of the form [M(PR3)2(NO)]+ (M = Pd, Pt; R = tBu, Ad) are reported. These diamagnetic nitrosyls are obtained from monovalent or zerovalent precursors by treatment with NO and NO+, respectively, and are notable for distinctly bent M-NO angles of ∼123° in the solid state. Adoption of this coordination mode in solution is also supported by the analysis of isotopically enriched samples by 15N NMR spectroscopy. Effective oxidation states of M0/NO+ are calculated, and metal-nitrosyl bonding has been interrogated using DFT-based energy decomposition analysis techniques. While a linear nitrosyl coordination mode was found to be electronically preferred, the M-NO and P-M-P angles are inversely correlated to the extent that binding in this manner is prevented by steric repulsion between the bulky ancillary phosphine ligands.</style></abstract><issue><style face="normal" font="default" size="100%">4</style></issue></record></records></xml>