<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Tsoureas, Nikolaos</style></author><author><style face="normal" font="default" size="100%">Kilpatrick, Alexander F.R.</style></author><author><style face="normal" font="default" size="100%">Summerscales, Owen T.</style></author><author><style face="normal" font="default" size="100%">Nixon, John F.</style></author><author><style face="normal" font="default" size="100%">Cloke, F. Geoffrey N.</style></author><author><style face="normal" font="default" size="100%">Hitchcock, Peter B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">The first example of the two-electron reduction of a phosphaalkyne - Synthesis and structural characterisation of the diuranium(IV) pentalene complex [(U{η5-C5Me5}{η8-C 8H4(SiiPr3-1,4)2}) 2(μ-η2:η1-tBuCP)]</style></title><secondary-title><style face="normal" font="default" size="100%">European Journal of Inorganic Chemistry</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Phosphaalkynes</style></keyword><keyword><style  face="normal" font="default" size="100%">Reduction</style></keyword><keyword><style  face="normal" font="default" size="100%">sandwich complexes</style></keyword><keyword><style  face="normal" font="default" size="100%">Uranium</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">2013</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">Wiley-VCH Verlag</style></publisher><pages><style face="normal" font="default" size="100%">4085 - 4089</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">The facile two-electron reduction of the phosphaalkyne tBuC=P by the U III cyclopentadienyl-pentalene mixed-sandwich complex [U(η5-C5Me5){η8-C 8H4(SiiPr3)2}] is reported. A single-crystal X-ray structural analysis of the diuranium(IV) product [(U{η5-C5Me5}{η8-C 8H4(SiiPr3)2})2(μ- tBuCP)] shows that it contains a slightly unsymmetrical, bridging μ-η2:η1- ligated phosphaalkene dianion. © 2013 Wiley-VCH Verlag GmbH &amp; Co. KGaA, Weinheim.</style></abstract><issue><style face="normal" font="default" size="100%">22-23</style></issue></record></records></xml>