Abstract:

This study examines the impact of light absorption from biomass burning (BB) brown carbon (BrC) in the Mediterranean basin from local and distant fire incidents during a typical fire season in August 2019 and under severe fire activity in August 2021. The approaches of Saleh et al. (2014) and Wang et al. (2018) are used to describe the BrC absorption within the WRF-Chem model. Focusing on three regions in the Mediterranean (around the islands of Sicily, Malta, and Crete) that are most affected by BB activity, BrC absorption approximates 5 Mm−1 in OC concentrations up to 3 μg m−3 and can approach 15 Mm−1 in extreme conditions (up to 10 μg m−3). When photochemical bleaching is considered, BrC undergoes almost immediate bleaching upon emission due to high levels of OH radical in the Mediterranean atmosphere during summertime, decreasing light absorption between 56% and 75% under both average and extreme BB conditions. Cloud formation is facilitated above the PBL due to moisture increase induced by BrC at the area of fire events, while transported drier and warmer air masses tend to dissipate cloud formation further away from the BB source. The impact of BrC absorption on irradiances is small (up to −6 W m−2 in extreme conditions) and is often overlapped by the absorption from water vapour variations. BrC direct radiative effect (DRE) is estimated at 0.04 W m−2 (∼10% of BC) in average and 0.18 W m−2 in extreme BB activity under clear sky. Under all sky, low-level clouds dissipation in 2019 with average BB emissions enhances DRE (at 0.15 W m−2), while the higher clouds dissipation in 2021 limits DRE (at 0.11 W m−2) resulting in lower DRE despite the extreme BB conditions.

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