Temperature dependence of the EPR spectra of EuBa2Cu3O7-δ in orthorhombic and tetragonal phases

Citation:

Guskos N, Calamiotou M, Londos CA, Likodimos V, Koufoudakis A, Mitros C, Gamari-Seale H, Niarchos D. Temperature dependence of the EPR spectra of EuBa2Cu3O7-δ in orthorhombic and tetragonal phases. Journal of Physics and Chemistry of Solids [Internet]. 1992;53:211-213.

Abstract:

EPR spectra between 9.7 K and room temperature (RT) were taken for EuBa2Cu3O7-δ in tetragonal and orthorhombic phases. Our results indicate significant differences between the EPR spectra of Cu2+ ions in the tetragonal and orthorhombic phase. It is concluded that in the tetragonal phase, the Cu2+ complex has axial symmetry. Furthermore, at low temperatures the observed EPR signal is associated with superexchange interaction between Eu2+ ions across oxygen bridges. © 1991.

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