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Double addition of H2 to transition metal-borane complexes: A “hydride shuttle” process between boron and transition metal centres

Citation:

Tsoureas N, Yu-Ying K, Haddow MF, Owen GR. Double addition of H2 to transition metal-borane complexes: A “hydride shuttle” process between boron and transition metal centres. Chemical Communications. 2011;47(1):484 - 486.

Abstract:

The addition of H2 across a transition metal-borane bond is reported for the first time providing a mechanism for recharging borane functional groups to borohydride. © 2010 The Royal Society of Chemistry.