Citation:
Tsoureas N, Haddow MF, Hamilton A, Owen GR. A new family of metallaboratrane complexes based on 7-azaindole: B-H activation mediated by carbon monoxide. Chemical Communications. 2009;(18):2538 - 2540.
Abstract:
The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl) 3}-] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units. © The Royal Society of Chemistry 2009.
