Citation:
Evans J, Levason W, Manning JM, Reid G, Tsoureas N, Webster M. Reversible structural isomerisation in rare thioether complexes of cobalt(ii) - Effects of ligand architecture. Dalton Transactions. 2007;(20):1986 - 1988.
Abstract:
Rare examples of (high spin) Co(ii) complexes with geometrically constrained tetrathioether ligands exhibit a very unusual structural isomerism, switching reversibly between tetrahedral monomers in solution and octahedral chain polymers in the solid; the crystal structures of one polymeric species and a tetrahedral monomer model compound are described. © The Royal Society of Chemistry.
